Catalytic Reductive Vinylidene Transfer Reactions
收藏NIAID Data Ecosystem2026-03-10 收录
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Methylenecyclopropanes are important synthetic intermediates that possess strain energies exceeding those of saturated cyclopropanes by >10 kcal/mol. This report describes a catalytic reductive methylenecyclopropanation reaction of simple olefins, utilizing 1,1-dichloroalkenes as vinylidene precursors. The reaction is promoted by a dinuclear Ni catalyst, which is proposed to access Ni2(vinylidenoid) intermediates via CCl oxidative addition.
创建时间：
2017-08-16
