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Photoredox-Catalyzed Hydrosulfonylation of Arylallenes

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NIAID Data Ecosystem2026-03-11 收录
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(Het)­Arylallenes undergo hydrosulfonylation under photoredox-catalyzed conditions. The reaction gives vinyl sulfones in a regio- and diastereoselective manner, employing sodium sulfinates as the sulfonyl source and eosin Y as the photocatalyst. Indol-1-yl, pyrrol-1-yl, phenyl, and naphtylallenes might be used. Aliphatic allenes are incompatible with the reaction conditions.

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2019-12-24
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