Formation of a Palladium Thioketone Complex from a Thiophosphinoyl Stabilized Li/Cl Carbenoid
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An in situ generated thiophosphinoyl stabilized Li/Cl carbenoid reacts with Pd(PPh3)4 with formation of a palladium thioketone complex. The presence of both the thiophosphinoyl and silyl groups as anion-stabilizing substituents is insufficient to stabilize the expected alkylidene complex and instead results in a rearrangement to the thioketone compound.
创建时间：
2016-02-23
