Substituent-Dependent Formation of Organotransition-Metal Bimetallic Calix[4]arene Inclusion Complexes
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Reaction of 1,3-di-O-substituted calixarene ligands with Et2Zn gives new organotransition-metal bimetallic calix[4]arene inclusion complexes when the substituent is larger than methyl. The resulting complexes show strong interactions between the incorporated organometallic fragment and the hydrophobic cavity of the calixarene group.
创建时间：
2004-09-27
