An Organically Templated Cobalt−Vanadium Oxide with β Cage Units: Hydrothermal Synthesis and X-ray Structural Characterization of (C<sub>2</sub>H<sub>10</sub>N<sub>2</sub>)[Co<sub>2</sub>(C<sub>2</sub>O<sub>4</sub>)V<sub>4</sub>O<sub>12</sub>]
收藏NIAID Data Ecosystem2026-03-06 收录
数据链接：
官方服务：
资源简介：
A novel organically templated cobalt-vanadium oxalate, (C2H10N2)[Co2(C2O4)V4O12], was synthesized under mild hydrothermal conditions and characterized by single-crystal/powder X-ray diffraction, infrared spectroscopy, and thermogravimetric analysis. The compound crystallizes in an orthorhombic system with space group Cmcm and cell parameters a = 11.527(2) Å, b = 9.9476(18) Å, c = 14.780(3) Å. The compound possesses 3-dimensional topologies with sodalite analogue structure and is constructed by C2O4-incorporated β cage units. On the basis of the results of TG/DTA analyses, the structure is thermally stable up to ∼573 K.
创建时间：
2016-08-17
