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Theory-Guided Discovery of Unique Chemical Transformations of Cyclopropenes

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NIAID Data Ecosystem2026-03-06 收录
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Chiral 2-cyclopropenyl-4-tolyl sulfones, available by the [2 + 1]-cycloaddition of tosyldiazomethane to acetylenes under catalysis by the Rh(II) complex 1, provide a number of unusual transformations and useful chiral products. This chemistry is dominated by the unusual strain and reactivity of the cyclopropene ring system.

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2016-05-12
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