Plasma-mediated synthesis of rhenium nanoparticles as a cost-effective alternative to platinum nanoparticles for nitroaromatic compounds hydrogenations

The colletion contains a set of data related to the synthesis of rhenium and platinum nanoparticles and their application in the processes of nitroaromatic compounds hydrogenation.The research was carried out within Sonata 16 (UMO-2020/39/D/ST8/01352), and Opus 25 (UMO-2023/49/B/ST8/01029) projects granted by National Science Center (Poland). One of the aims of these projects is to develop new generation of nanocatalysts based on d-block elements nanoparticles for the catalytic hydrogenations.The set of data contains:Raw images and EDX spectra obtained during transmission electron microscopy analysis.UV-Vis spectra recorded during catalytic reductions of 4-nitrophenol, 4-nitroaniline, 2-nitroaniline, 2,4-dinitrophenol, nitrobenzene, and 2,4,6-trinitrophenolXPS spectra (survey and high resolution) of the samples containing metallic nanoparticles

本数据集收录了与铼、铂纳米颗粒合成及其在硝基芳烃类化合物加氢反应中的应用相关的一系列实验数据。本研究依托波兰国家科学中心资助的Sonata 16（UMO-2020/39/D/ST8/01352）与Opus 25（UMO-2023/49/B/ST8/01029）项目开展。上述项目的核心目标之一，是开发基于d区元素纳米颗粒的新一代纳米催化剂，用于催化加氢反应。本数据集包含以下内容：
1. 透射电子显微镜（Transmission Electron Microscopy, TEM）分析过程中获取的原始图像与能量色散X射线光谱（Energy Dispersive X-ray Spectroscopy, EDX）；
2. 催化还原4-硝基苯酚、4-硝基苯胺、2-硝基苯胺、2,4-二硝基苯酚、硝基苯及2,4,6-三硝基苯酚过程中记录的紫外-可见光谱（Ultraviolet-Visible spectroscopy, UV-Vis）；
3. 含金属纳米颗粒样品的X射线光电子能谱（X-ray Photoelectron Spectroscopy, XPS，包含全谱与高分辨谱）。

搜集汇总

背景与挑战

背景概述

该数据集聚焦于通过等离子体介导方法合成铼纳米颗粒，旨在作为铂纳米颗粒的低成本替代品，用于硝基芳香化合物的氢化反应。数据集包含透射电子显微镜图像、EDX光谱、UV-Vis光谱和XPS光谱等实验数据，支持催化性能研究。这些数据来源于波兰国家科学中心资助的研究项目，旨在开发基于d区元素纳米颗粒的新一代纳米催化剂。