Several organosilicon compounds bearing a 2-(phenylazo)phenyl group were synthesized from the corresponding chlorosilanes and 2-lithioazobenzene prepared by halogen−lithium transmetalation of 2-iodoaz
Two diastereomeric crystalline steroid dimers were obtained by acid-catalyzed double acetalization of (20S)-5α-pregnan-3β,16β,20-triol 3-monoacetate with terephtalaldehyde. These compounds were charac
Self-assembly of a cis-blocked Pd(II) 90° ditopic acceptor [cis-(tmeda)Pd(NO3)2] (M) with a tetradentate donor L1 [benzene-1,4-di(4-terpyridine)] in 2:1 molar ratio yielded two isometric molecular
Supramolecular gels are a class of soft materials formed by the self-assembly of small molecules, exhibiting versatile properties and responsiveness to external stimuli. Understanding their self-assem