A 3‑Fold-Symmetric Ligand Based on 2‑Hydroxypyridine: Regulation of Ligand Binding by Hydrogen Bonding
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A tripodal ligand based on 2-hydroxypyridine is presented. Cu–Cl adducts of H3thpa with CuI and CuII provide complexes featuring highly directed, intramolecular hydrogen-bonding interactions. An upper limit for the hydrogen-bonding free energy to CuI–Cl was estimated at ∼18 kcal/mol.
创建时间：
2016-02-17
