Double Metalation of Acetone by a Nickel–NHC Complex: Trapping of an Oxyallyl Ligand at a Dinickel Center
收藏NIAID Data Ecosystem2026-03-07 收录
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We report the first example of a structurally characterized oxyallyl −CH2C(O)CH2– group, trapped as a bridging ligand that spans two nickel centers. The ligand results from the double metalation of acetone on a nickel–NHC platform. A competing reaction leads to a single metalation of acetone.
创建时间：
2016-02-22
