A Homogeneous Gallium(III) Compound Selectively Catalyzes the Epoxidation of Alkenes
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We demonstrate that a simple gallium(III) complex, [Ga(phen)2Cl2]Cl (phen = 1,10-phenanthroline), can serve as a homogeneous catalyst for the epoxidation of alkenes. The olefin epoxidations proceed relatively quickly at mild temperatures and, under optimum conditions, are highly selective for the epoxide product.
创建时间：
2012-03-05
