Enantioselective α‑Arylation of <i>O</i>‑Carbamates via Sparteine-Mediated Lithiation and Negishi Cross-Coupling
收藏NIAID Data Ecosystem2026-03-10 收录
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资源简介：
A general and highly enantioselective arylation of carbamates derived from primary alcohols was developed by combining Hoppe’s sparteine-mediated asymmetric lithiation with Negishi cross-coupling. Coupled with Aggarwal’s lithiation–borylation sequence, the current method provides a short and divergent access to a variety of enantioenriched secondary and tertiary benzylic alcohols.
创建时间：
2016-12-19
