SmI<sub>2</sub>-Promoted Intramolecular Asymmetric Pinacol-Type Ketone−<i>tert</i>-Butanesulfinyl Imine Reductive Coupling: Stereoselectivity and Mechanism
收藏NIAID Data Ecosystem2026-03-06 收录
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The asymmetric ketone−tert-butanesulfinyl (t-BS) imine pinacol-type reductive coupling promoted by SmI2 is described. Trans-1,2-vicinal amino alcohols were formed predominantly in excellent er and high dr. The stereochemical outcome provided evidence for a radical mechanism for SmI2-induced reductive couplings of t-BS imines.
创建时间：
2016-02-26
