Rational Synthesis and Reversible Metal−Metal Bond Scission of Heterobimetallic Xenophilic Complexes Containing an Unsupported, Polar Metal−Metal Bond, Tp<sup>iPr</sup><sub><sup>2</sup></sub>M−Co(CO)<sub>3</sub>L (M = Ni, Co, Fe, Mn; L = CO, PPh<sub>3</sub>)
收藏NIAID Data Ecosystem2026-03-06 收录
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资源简介：
A series of heterobimetallic xenophilic complexes containing an unsupported polar metal−metal bond, TpiPr2M-Co(CO)4 (M = Ni, Co, Fe, Mn), is synthesized by treatment of the labile cationic species [TpiPr2M(NCMe)3]+ with PPN[Co(CO)4], and the polar nature of the metal−metal bond is characterized by spectroscopic and crystallographic methods as well as by the reaction with MeCN, causing metal−metal bond heterolysis to give the ion pairs [TpiPr2M(NCMe)3]+[Co(CO)4]-.
创建时间：
2016-08-26
