Facile Synthesis of Monoazidotitanium Isopropoxides
收藏NIAID Data Ecosystem2026-03-06 收录
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The monoazidotitanium trisisopropoxide {(N3)Ti(OiPr)3}4 (2) was obtained by the reaction of (N3)2Ti(OiPr)2 (1) with Ti(OiPr)4. Colorless 2 possesses an interesting tetrameric structure featuring bridging azide and isoproxide ligands and five- and six-coordinate titanium centers. It can be sublimed in vacuo at ca. 130 °C but decomposes rapidly above 180 °C. Controlled hydrolysis afforded the related yellow oxo cluster (iPrO)8Ti4(μ-OiPr)2(μ4-O)(μ-N3)4 (3).
创建时间：
2016-02-27
