The Highest-Nuclearity Manganese/Oximate Complex: An Unusual Mn<sup>II/III</sup><sub>15</sub> Cluster with an <i>S</i> = 6 Ground State
收藏NIAID Data Ecosystem2026-03-06 收录
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The synthesis, structure, and magnetochemical characterization of the largest manganese oxime cluster are reported. The Mn15/2-pyridinealdoxime compound is mixed-valence (II/III) and possesses an irregular structural motif with a novel Mn/O core. The oximato-bridged cluster exhibits an S = 6 ground state and a negative magnetoanisotropy.
创建时间：
2010-05-03
