Synthesis and Structures of Mo<sub>3</sub>Se<sub>7</sub>Te<sub>2</sub>Br<sub>10</sub>, Mo<sub>3</sub>Se<sub>7</sub>TeI<sub>6</sub>, and Mo<sub>6</sub>Te<sub>21</sub>I<sub>22</sub> Containing TeX<sub>3</sub><sup>-</sup> (X = Br, I) Ligands Coordinated to a Triangular Cluster Core<sup>†</sup>
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数据链接：
https://figshare.com/articles/dataset/Synthesis_and_Structures_of_Mo_sub_3_sub_Se_sub_7_sub_Te_sub_2_sub_Br_sub_10_sub_Mo_sub_3_sub_Se_sub_7_sub_TeI_sub_6_sub_and_Mo_sub_6_sub_Te_sub_21_sub_I_sub_22_sub_Containing_TeX_sub_3_sub_sup_sup_X_Br_I_Ligands_Coordinated_to_a_Triangular_Cluster_Core_s/3005062数据链接链接失效反馈
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资源简介：
New ternary and quaternary molybdenum cluster chalcohalides were obtained by high-temperature reactions between Mo, chalcogens, and halogens in evacuated ampules. The crystal structures of [Mo3Se7(TeBr3)Br2]2[Te2Br10] (1), [Mo3Se7(TeI3)I2]I (2), and [Mo3Te7(TeI3)3]2(I)(TeI3) (3) were determined by single-crystal X-ray diffraction. The structures of 1 and 2 consist of positively charged zigzag chains [Mo3Se7(TeX3)X4/2] (X = Br, I), with Te2Br102- and I-, respectively, as counterions. The TeI3- and TeBr3- ions function as bidentate ligands in 1 and 2. In 3, TeI3- is not coordinated to the metal but acts as a counterion to the [Mo3Te7(TeI3)3]+ cluster cation.
创建时间：
2016-07-05
