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Discrete Iridamacrocycle Formation via C–H Activation of an N-Heterocycle

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NIAID Data Ecosystem2026-03-07 收录
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An N-heterocycle (pyrazine) utilized as a precursor was employed to construct multinuclear metallamacrocycle 1 though C–H activation and metal–metal bond formation under mild conditions. This iridamacrocycle was fully characterized by 1H NMR, IR, and elemental analysis. In order to further confirm its structure, X-ray analysis was carried out, proving the hexanuclear iridium macrocyclic backbone of the complex.

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2016-02-23
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