Photocatalytic systems developed from complexes with only abundant metals, i.e., CuI(dmp)(P)2+ (dmp =2,9-dimethyl-1,10-phenanthroline; P = phosphine ligand) as a redox photosensitizer and FeII(dmp)2(
Construction of metal-mediated redox sites is an appealing approach to enhance photocatalytic CO2 reduction coupled with H2O oxidation. However, conventional static redox sites generally lack spatiote
Improving the photocatalytic efficiency of a fully noble-metal-free system for CO2 reduction remains a fundamental challenge, which can be accomplished by facilitating electron delivery as a consequen
The valorization of CO2 via photo- or electrocatalytic reduction constitutes a promising approach toward the sustainable production of fuels or value-added chemicals using intermittent renewable energ
Reductive hydrosilylation of CO2 by catalysts based on environmentally benign metals such as zinc still presents an unmet challenge in terms of catalyst selectivity and activity. Here we show that tet