Exploring the Assembly of Supramolecular Polyoxometalate Triangular Morphologies with Johnson Solid Cores: [(Mn<sup>II</sup>(H<sub>2</sub>O)<sub>3</sub>)<sub>2</sub>(K⊂{α-GeW<sub>10</sub>Mn<sup>II</sup><sub>2</sub>O<sub>38</sub>}<sub>3</sub>)]<sup>19–</sup>
收藏NIAID Data Ecosystem2026-03-07 收录
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A new polyoxometalate (POM) cluster compound is presented which incorporates a trimeric assembly of Keggin-type germanotungstate fragments trapping a Johnson-type solid {Mn8} core. The mixed K–Li salt of the polyanion [(MnII(H2O)3)2(K⊂{α-GeW10MnII2O38}3)]19– was characterized in the solid state and solution. The correlation of the assembly processes and the observed architecture of the “trinity” family of POMs is discussed.
创建时间：
2013-08-19
