A new tridentate ligand, PYAN, is employed to investigate solvent influences for dioxygen reactivity with [Cu(PYAN)(MeCN)]B(C6F5)4 (1). Stopped-flow kinetic studies confirm that the adducts [{CuII(PYA
The complexes trans-[RuIII(NH3)4(4-pic)(H2O)](CF3SO3)3 (1) and [RuIII(NH3)5(4-pic)](CF3SO3)3 (2) were isolated and studied experimentally by electron paramagnetic resonance (EPR) and UV–vis spectro
Comparison of the TD-DFT transitions of NSC724998 compound, in CCl4 and DMSO, with the experimental UV-Vis absorption peaks, cfr. Fig. 3. astr: strong, w: weak, sh: shoulder.
The nature of H(H2O)n+ cations for n = 3−8 with weakly basic carborane counterions has been studied by IR spectroscopy in benzene and dichloroethane solution. Contrary to general expectation, neither