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Self-Assembled Containers Based on Extended Tetrathiafulvalene

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NIAID Data Ecosystem2026-03-09 收录
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Two original self-assembled containers constituted each by six electroactive subunits are described. They are synthesized from a concave tetratopic π-extended tetrathiafulvalene ligand bearing four pyridyl units and cis-M­(dppf)­(OTf)2 (M = Pd or Pt; dppf = 1,1′-bis­(diphenylphosphino)­ferrocene; OTf = trifluoromethane-sulfonate) complexes. Both fully characterized assemblies present an oblate spheroidal cavity that can incorporate one perylene molecule.

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2016-02-19
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