New Three-Dimensional Metal−Organic Framework with Heterometallic [Fe−Ag] Building Units: Synthesis, Crystal Structure, and Functional Studies
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A new three-dimensional metal−organic framework (MOF) containing FeII and AgI ions and 2-pyrazinecarboxylic acid (pcaH) was synthesized, and its magnetic and catalytic properties were studied. The MOF has a big window size of 12.1 × 12.0 Å, with 23.8% solvent-accessible space, and shows size selectivity toward Lewis acid catalysis.
创建时间:
2016-02-23



