Acid-Mediated Intermolecular [3 + 2] Cycloaddition toward Pyrrolo[2,1‑<i>a</i>]isoquinolines: Total Synthesis of the Lamellarin Core and Lamellarin G Trimethyl Ether
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A novel one-pot reaction has been developed for the efficient synthesis of pyrrolo[2,1-a]isoquinolines and 1-dearyllamellarin core from (E)-(2-nitrovinyl)benzenes and azomethine ylides generated in situ. This strategy provides a concise total synthesis of the lamellarin core and lamellarin G trimethyl ether using electrophilic substitution and palladium-catalyzed Suzuki–Miyaura cross-coupling reactions.
创建时间：
2017-04-19
