Formation of Coordinated <i>C</i>-Nitroso Compounds by Reaction of K[IrCl<sub>5</sub>NO] with Alkenes
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Coordinated C-nitrosochloroalkanes were obtained by electrophilic addition of K[IrCl5NO] to cyclooctene or dicyclopentadiene; in the last case, the crystal structure of trans-[IrCl4(CH3CN)(syn-1-chloro-2-nitroso-1,2-dihydrodicyclopentadiene)] was determined by X-ray diffraction. Although the reaction between NOCl and alkenes is well-known, there are very few examples of clean electrophilic addition of coordinated NO+ to alkenes.
创建时间：
2016-03-01
