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Tautomerization in Naphthalenediimines: A Keto-Enamine Schiff Base Macrocycle

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NIAID Data Ecosystem2026-03-06 收录
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A new [3 + 3] Schiff base macrocycle incorporating naphthalene groups has been prepared. By examination of its properties, X-ray crystallography of model compounds, and calculations, it has been determined that the macrocycle exists predominantly as the keto-enamine tautomer. This unexpected tautomerization presents an unusual hexaketo interior in the macrocycle.

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2016-05-05
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