Regio- and Diastereoselective Nickel-Catalyzed Allylation of Aromatic Aldehydes with α‑Halo-β,β-difluoropropene Derivatives
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A one-pot nickel-catalyzed allylation of aromatic aldehydes with α-halo-β,β-difluoropropene-containing compounds promoted by ZnEt2 under mild conditions was described. The reaction displays moderate to good regio- and diastereoselectivity, tolerates a wide range of functional groups, and provides an efficient method for the synthesis of γ-fluorinated homoallylic alcohols.
创建时间：
2016-02-20
