Complete separation of benzene-cyclohexene-cyclohexane mixtures via temperature-dependent molecular sieving by a flexible chain-like coordination polymer
This paper reports eight novel one-dimensional (1D) helical chain polymers consisting of metal salts and flexible bis(imidazole) ligands, formulated as [Co(L1)2(bimb)] (1), [Cu2(bimb)2Cl2] (2), [Co(L2
Two types of new d–f heterometallic coordination frameworks, [Ln2M(μ3-HPyIDC)2(ox)2(H2O)4]·4H2O [Ln = Sm, M = Co (1); Ln = Sm, M = Fe (2); Ln = Eu, M = Co (3); Ln = Eu, M = Fe (4); Ln = Gd, M = Co (5
In this study, two new coordination polymers based on Cu(II) and Co(II) ions as the metal nodes, {Cu(3-PPT) 2 ]·H 2 O} n ( 1 ) and {[Co(3-PPT) 2 ]·3CH 3</
[2.2]Paracyclophane scaffolds have seen limited use as building blocks in supramolecular chemistry. Here, we report the synthesis and characterization of a 1D coordination polymer consisting of silver