Reversible Cleavage and Recombination of an Acetylenic Carbon−Carbon Bond on a Tetrairon Cluster Coupled with a Two-Electron Redox Reaction
收藏NIAID Data Ecosystem2026-03-06 收录
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Two-electron reduction of [(η5-C5H4Me)4Fe4(μ3-CH)2(μ3-CO)2](PF6)2 (1) results in the coupling of two methylidyne ligands to form (η5-C5H4Me)4Fe4(HCCH)(μ3-CO)2 (2), the two-electron oxidation of which reproduces 1. Structures of 1 and 2 were determined by X-ray diffraction analysis.
创建时间：
2016-05-07
