Total Synthesis of the Antitumor Depsipeptide FR-901,228

NIAID Data Ecosystem2026-03-06 收录

抗肿瘤药物合成

天然产物合成

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Total Synthesis of the Antitumor Depsipeptide FR-901,228

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2016-08-18

Development of a Concise Synthesis of (+)-Ingenol

天然产物合成

药物开发

The complex diterpenoid (+)-ingenol possesses a uniquely challenging scaffold and constitutes the core of a recently approved anti-cancer drug. This full account details the development of a short syn

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Expedient Construction of the Vibsanin E Core without the Use of Protecting Groups

天然产物合成

有机合成方法

The tricyclic core of vibsanin E was constructed without the use of a protecting group in six steps. The El Gaïed Baylis−Hillman variant was key to allowing the Brønsted acid induced tandem cyclizatio

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Stereoselective Total Syntheses of Guanacastepenes N and O

天然产物合成

有机合成方法

Total syntheses of (±)-guanacastepenes N and O were accomplished with 2-cycloheptenone as starting material. The six- and five-membered rings of the core [5, 7, 6] ring skeleton were constructed with

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Progress toward the Total Synthesis of (±)-Havellockate

天然产物合成

二萜生物合成

Havellockate (1) was isolated from the soft coral Sinularia granosa located on the Havellock island in the Indian Ocean. This highly compact and polyoxygenated marine diterpene bears a cis-fused hydri

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Selective Oxidations in the Synthesis of Complex Natural ent -Kauranes and ent -Beyeranes

天然产物合成

选择性氧化反应

Syntheses of two natural products derived from the ent-kaurene kaurenoic acid are described for the first time using regio- and diastereoselective oxidations. Palladium- and manganese-mediated oxidati

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Total Synthesis of the Antitumor Depsipeptide FR-901,228

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