基于零价铁双氧水体系构建还原氧化耦合技术及反应机理研究

该数据集包括零价铁/双氧水体系还原-氧化耦合去除对硝基氯苯(p-CNB)活性测试、工艺优化以及机理探究；草酸化零价铁还原-氧化耦合性能评价、还原物种检测以及反应机理研究；硼化零价铁还原-氧化耦合性能评价及反应机理研究；磷酸化零价铁还原-氧化耦合去除有机砷性能评价及反应机理研究；还原氧化耦合技术的辅助材料开发。本部分系统评估了小分子配体改性零价铁用于还原氧化耦合技术的可行性，证明其可高效降解去除多种污染物。This dataset covers: 1) activity testing, process optimization and mechanism investigation of the zero-valent iron/hydrogen peroxide reductive-oxidative coupling system for p-chloronitrobenzene (p-CNB) removal; 2) performance evaluation, reductive species detection and reaction mechanism studies of oxalate-modified zero-valent iron applied in reductive-oxidative coupling; 3) performance evaluation and reaction mechanism studies of borated zero-valent iron for reductive-oxidative coupling; 4) performance evaluation and reaction mechanism studies of phosphorylated zero-valent iron for reductive-oxidative coupling removal of organic arsenic; and 5) development of auxiliary materials for reductive-oxidative coupling technology. This section systematically evaluates the feasibility of small-molecule ligand-modified zero-valent iron used in reductive-oxidative coupling technology, and verifies that it can efficiently degrade and remove various pollutants.

搜集汇总

背景与挑战

背景概述

该数据集围绕零价铁/双氧水体系，系统研究了还原-氧化耦合技术去除有机污染物的性能、工艺优化及反应机理。它通过评估小分子配体改性零价铁的可行性，证明了该技术可高效降解多种污染物。