Photoassisted “Gate-Lock” Fluorescence “Turn-on” in a New Schiff Base and Coordination Ability of <i>E–Z</i> Isomers
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Rapid photoresponse (1.0–8.0 min) through fluorescence “turn-on” signaling displayed by a novel Schiff base (L) creating “gate lock” via intramolecular C–H···N interaction in photoisomerized product (L′) has been described. Coordination chemistry of pre- and postirradiated species demonstrated a drastic change in the reactivity which has been supported by NMR, HRMS, UV–vis, emission, electrochemical, and complexation studies.
创建时间：
2016-02-22
