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Nitroxide-Substituted Nitronyl Nitroxide and Iminonitroxide

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NIAID Data Ecosystem2026-03-06 收录
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We report on the highly compact nitroxide-substituted nitronyl nitroxide 1 and iminonitroxide 2; they have isoelectronic structures with trimethylenemethane. These diradicals are stable under aerated conditions at room temperature and have large positive exchange interactions: J/kB = +390 K (H = −2JS1/2·S1/2) for 1 and J/kB ≈ +550 K for 2.

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2010-11-17
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