Catalytic Direct Acetoxylation of Indoles

NIAID Data Ecosystem2026-03-06 收录

C-H键活化催化

吲哚衍生物合成

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https://figshare.com/articles/dataset/Catalytic_Direct_Acetoxylation_of_Indoles/2827108 数据链接链接失效反馈

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资源简介：

3-Acetoxyindole-2-carboxylates could be readily synthesized in a Pd(OAc)2- or PtCl2-catalyzed direct C-3 acetoxylation of indole-2-carboxylates using PhI(OAc)2 as a terminal oxidant.

创建时间：

2009-09-18

Isolation of Key Organometallic Aryl-Co(III) Intermediates in Cobalt-Catalyzed C(sp 2 )–H Functionalizations and New Insights into Alkyne Annulation Reaction Mechanisms

C-H键活化催化

炔烃环化反应机理

The selective annulation reaction of alkynes with substrates containing inert C–H bonds using cobalt as catalyst is currently a topic attracting significant interest. Unfortunately, the mechanism of t

NIAID Data Ecosystem60

Palladium(II)-Catalyzed Direct Ortho Arylation of 4‑Methyl‑ N ‑phenylpyridin-2-amines via C–H Activation/C–C Coupling and Synthetic Applications

有机合成方法

C-H键活化催化

The direct ortho arylation of 4-methyl-N-phenylpyridin-2-amines via palladium(II)-catalyzed C–H activation is described. Treatment of 4-methyl-N-phenylpyridin-2-amine with potassium aryltrifluorobora

NIAID Data Ecosystem50

Identification and Reactivity of Cyclometalated Iron(II) Intermediates in Triazole-Directed Iron-Catalyzed C–H Activation

C-H键活化催化

有机中间体表征

While iron-catalyzed C–H activation offers an attractive reaction methodology for organic transformations, the lack of molecular-level insight into the in situ formed and reactive iron species impedes

NIAID Data Ecosystem40

Pt-Catalyzed C–C Activation Induced by C–H Activation

C-H键活化催化

有机反应机理

The catalytic cleavage of two C–C single bonds is achieved by treatment of the hydrocarbon substrate spiro[bicyclo[2.2.1]hept-2-ene-7,1′-cyclopropane] with Pt(II) catalysts such as (Me2bpy)PtPh(N

NIAID Data Ecosystem50

Synthesis, Photophysical, and Electrochemical Properties of Pyrenes Substituted with Donors or Acceptors at the 4- or 4,9-Positions

有机光电材料

吲哚衍生物合成

We report herein an efficient and direct functionalization of the 4,9-positions of pyrene by Ir-catalyzed borylation. Three pinacol boronates (-Bpin), including 4-(Bpin)-2,7-di(tert-butyl)pyrene (5)

NIAID Data Ecosystem50

Catalytic Direct Acetoxylation of Indoles

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