Bile Acid-Based Cage Compounds with Lipophilic Outer Shells and Inner Cavities
收藏NIAID Data Ecosystem2026-03-07 收录
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The uniquely functionalized steroid-based cyclodimers 4, cis-5, and trans-5 have been synthesized and fully characterized.The cyclodimer 5, with a cis–trans ratio of 3:1, is obtained by coupling the terminal alkenes of two 4-pentenoate groups on a cyclodimer 4 via Grubbs’ intramolecular ring-closing metathesis. The crystal structure shows cis-5 to be a cagelike cyclic oligomer bridged by the flexible oct-4-enedioate link.
创建时间：
2011-06-17
