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Reduction of (Diiminopyridine)iron: Evidence for a Noncationic Polymerization Pathway?

NIAID Data Ecosystem2026-03-06 收录

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https://figshare.com/articles/dataset/Reduction_of_Diiminopyridine_iron_Evidence_for_a_Noncationic_Polymerization_Pathway_/3251134 数据链接链接失效反馈

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A formally zerovalent Fe complex gave, upon activation, the same catalytic activity as the divalent precursor.

应用场景：

创建时间：

2016-05-05

氢化催化

铁配合物催化

A series of iron(II) complexes, trans-[Fe(NCMe)2(PR2CH2CHNCH2CH2NCHCH2PR2)][BPh4]2 (5, R = Cy; 7, R = iPr; 9, R = Et) were prepared via the template synthesis in one-pot involving air-stable phospho

NIAID Data Ecosystem30

Electron-Deficient Iron Alkyl Complexes Supported by Diimine Ligand (Ph 2 CN) 2 C 2 H 4 : Evidence for Reversible Ethylene Binding

乙烯可逆结合

铁配合物催化

Reaction of diimine ligands (Ph2CN)2CnH2n (n = 2, a; n = 3, b) with FeCl2 or FeBr2 results in formation of the corresponding high-spin ferrous complexes {(Ph2CN)2C2H4}FeX2 (1a, X = Cl; 2a, X = Br) and

NIAID Data Ecosystem30

Supporting Data for “Why So Slow? Mechanistic Insights from Studies of a Poor Catalyst for Polymerization of ε-Caprolactone”

聚合反应机理

催化剂优化

These files contain data along with associated output from instrumentation supporting all results reported in Stasiw, D. E.; Mandal, M.; Neisen, B. D.; Mitchell, L. A.; Cramer, C. J.; Tolman, W. B. Wh

DataCite Commons2022-03-08 更新30

Hydroboration of Alkynes Catalyzed by Pyrrolide-Based PNP Pincer–Iron Complexes

烯烃氢硼化

铁配合物催化

To utilize iron complexes as catalysts, the application of a well-designed ligand is critical to control the reactivity of the iron center. Recently, our group has succeeded in the synthesis of iron c

NIAID Data Ecosystem30

A Computational Analysis of the Ring-Opening Polymerization of r ac -Lactide Initiated by Single-Site β-Diketiminate Metal Complexes: Defining the Mechanistic Pathway and the Origin of Stereocontrol

立体选择性聚合

聚合反应机理

The ring-opening polymerization of rac-lactide at a β-diketiminate magnesium center, [HC{CMeN-2,6-iPr2C6H3}2]Mg(OMe)(THF), has been investigated using a B3-LYP density functional procedure employing t

NIAID Data Ecosystem30

Reduction of (Diiminopyridine)iron: Evidence for a Noncationic Polymerization Pathway?

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