Herein, we demonstrate that the incorporation of an acidic hydrogen-bond-donating squaramide moiety into a porous UiO-67 metal–organic framework (MOF) derivative leads to dramatic acceleration of the
A series of carbene–diether ligands were prepared and the corresponding Ag salts used to prepare the complexes RuHCl(PPh3)2(Im(OR)2) (Im(OR)2 = C3H2(NCH2CH2OR)2; R = Me (4a), t-Bu (4b), tert-hexyl
Zirconium-based metal–organic frameworks (Zr-MOFs) have been increasingly studied over the past two decades as heterogeneous catalysts due to their synthetic tunability, well-defined nature, and chemi
We report the synthesis and characterization of a series of nickel complexes of the chelating diphosphine-borane ligands ArB(o-Ph2PC6H4)2 ([ArDPBPh]; Ar = Ph, Mes). The [ArDPBPh] framework supports p
16-Electron iridium complexes bearing a silyl-1,8-naphthyridine-based bidentate ligand (napySi), Ir(κ2Si,N-napySi)(H)(coe)X [X = Cl (1) and Me (2)], were synthesized and characterized. Single-crystal
