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A New Polycatenated 3D Array of Interlaced 2D Brickwall Layers and 1D Molecular Ladders in [Mn<sub>2</sub>(bix)<sub>3</sub>(NO<sub>3</sub>)<sub>4</sub>]·2CHCl<sub>3</sub> [bix = 1,4-bis(imidazol-1-ylmethyl)benzene] That Undergoes Supramolecular Isomerization upon Guest Removal

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NIAID Data Ecosystem2026-03-06 收录
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The reactions of Mn(II) nitrate with the flexible ligand 1,4-bis(imidazol-1-ylmethyl)benzene (bix) (reagent ratios 1:2–1:3) yield novel interesting coordination networks including, besides the ladder-like species [Mn(bix)1.5(NO3)2] and the 2-fold interpenetrated three-dimensional (3D) cds network [Mn(bix)2(NO3)2], the exceptional [Mn2(bix)3(NO3)4]·2CHCl3, which is comprised of two different supramolecular isomers, namely, brickwall layers and one-dimensional (1D) molecular ladders, polycatenated to give a 3D (2D + 1D) architecture.

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2008-01-02
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