A New Polycatenated 3D Array of Interlaced 2D Brickwall Layers and 1D Molecular Ladders in [Mn<sub>2</sub>(bix)<sub>3</sub>(NO<sub>3</sub>)<sub>4</sub>]·2CHCl<sub>3</sub> [bix = 1,4-bis(imidazol-1-ylmethyl)benzene] That Undergoes Supramolecular Isomerization upon Guest Removal
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数据链接:
https://figshare.com/articles/dataset/A_New_Polycatenated_3D_Array_of_Interlaced_2D_Brickwall_Layers_and_1D_Molecular_Ladders_in_Mn_sub_2_sub_bix_sub_3_sub_NO_sub_3_sub_sub_4_sub_2CHCl_sub_3_sub_bix_1_4_bis_imidazol_1_ylmethyl_benzene_That_Undergoes_Supramolecular_Isomerization_upon_Guest_Rem/2965345数据链接链接失效反馈
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资源简介:
The reactions of Mn(II) nitrate with the flexible ligand 1,4-bis(imidazol-1-ylmethyl)benzene (bix) (reagent ratios 1:2–1:3) yield novel interesting coordination networks including, besides the ladder-like species [Mn(bix)1.5(NO3)2] and the 2-fold interpenetrated three-dimensional (3D) cds network [Mn(bix)2(NO3)2], the exceptional [Mn2(bix)3(NO3)4]·2CHCl3, which is comprised of two different supramolecular isomers, namely, brickwall layers and one-dimensional (1D) molecular ladders, polycatenated to give a 3D (2D + 1D) architecture.
创建时间:
2008-01-02



