Metal−Ligand Cooperativity in O<sub>2</sub> Activation: Observation of a “Pt−O−O−C” Peroxo Intermediate
收藏NIAID Data Ecosystem2026-03-06 收录
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The Pt(IV) complex (tBuMe2nacnac)PtMe3 (1, tBuMe2nacnac = [((4-tBu-2,6-Me2C6H2)NC(CH3))2CH]) reacts with molecular oxygen to form a peroxo complex, 2, in which one oxygen atom is bound to the platinum center and the other to the central carbon of the nacnac ligand backbone. Over time, 2 converts to a new Pt(IV) species (3) wherein the oxygen−oxygen bond has been cleaved.
创建时间：
2010-11-08
