Metal-Organic Frameworks (MOFs) are, according to IUPAC, coordination polymers with an open framework containing potential voids, which can be accessible after activation processes. These materials ha
Porous organic cages can act as hosts for the three-dimensional alignment of guests such as halogens and organometallics. Porous single crystals are doped by vapor sublimation to produce diamondoid ar
Mechanochemistry enables targeted, rapid synthesis of bimetallic metal–organic frameworks (MOFs) with a controlled 1:1 stoichiometric composition of metal nodes. In particular, ball milling enabled th
Sonication and radical attack are both known to contribute to breaking down polymers. Quantum chemical models show how the two can operate together, where radical attack is shown to reduce the effecti
The problem of capillary transport in fibrous porous materials at low levels of liquid saturation has been addressed. It has been demonstrated that the process of liquid spreading in this type of poro