Synthesis and Characterization of a Water Stable Uranyl(V) Complex
收藏NIAID Data Ecosystem2026-03-10 收录
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We have identified a polydentate aminocarboxylate ligand that stabilizes uranyl(V) in water. The mononuclear [UO2(dpaea)]X, (dpaeaH2 = Bis(pyridyl-6-methyl-2-carboxylate)-ethylamine; X = CoCp2*+ or X = K(2.2.2.cryptand) complexes have been isolated from anaerobic organic solution, crystallographically and spectroscopically characterized both in water and organic solution. These complexes disproportionate at pH ≤ 6, but are stable in anaerobic water at pH 7–10 for several days.
创建时间：
2018-10-12
