The reinvestigation of two allyl zinc compounds, parent bis(allyl)zinc [Zn(C3H5)2] (1) and 2-methallyl chloro zinc [Zn(C4H7)Cl] (2), revealed two new coordination modes in the solid state for the
Pincer complexes of 2,5-bis{(pyrrolidino)-methyl}-pyrrole with group 14 elements such as germanium, tin, and lead were prepared and fully characterized by X-ray single-crystal analysis, NMR spectrosc
Multidentate tripodal ligands, N(CH2-m-C6H4-CH2tacn)3 (L1) and N(CH2-o-C6H4-CH2N(CH2py)2)3 (L2), have been devised for assembling high-nuclearity metal clusters. By using the same tripodal platform wi
Two examples of N-aryloxy-β-diketiminate dianions (11a,b) have been synthesized on a multigram scale, in four steps, from commercially available chemicals. The synthetic scheme relies on the sequentia
