A potentially general strategy for accessing the rarely encountered coordination of amidoximates through both oximato O and amido N atoms was developed. The new amidoxime (Z)-R1C(NOH)NR2H (R1 = mesit
A series of nine porphyrin analogues have been synthesized using the “3 + 1” variant on the MacDonald condensation. Tripyrrane-type systems with a centrally unsubstituted pyrrole, furan, or thiophene
The metalloligand [Au{C(NHMe)(NHCH2CH2NH2)}2]Cl, 1, has been prepared by the reaction of ethylenediamine with [Au(CNMe)2]Cl. Compound 1 crystallized as a luminescent dimer with a Au···Au separation of
The crystal structures of [PtCl2(ttcn)], [PdCl2(ttcn)], [Pt(ethylenediamine)(ttcn)](PF6)2, and [Pd(ethylenediamine)(ttcn)](PF6)2 (ttcn = 1,4,7-trithiacyclononane) show short apical metal---S(ttcn) dis
The synthesis and characterization of two new polyazamacrocycles, 1,4,7,10-tetraaza[12](2,6)phenolphane (L1) and 1,4,7,10,13-pentaaza[15](2,6)phenolphane (L2), are reported. Both ligands incorporate t
