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Frustrated Lewis Pair Catalyzed S–H Bond Borylation

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NIAID Data Ecosystem2026-03-10 收录
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The frustrated Lewis pair (FLP) [NMe2-C6H4-BH2]2 is shown to catalyze the dehydrogenative borylation of thiols. The scope of the reaction, the experimental and computational investigation of the mechanism, and the application of the system to a one-pot Michael addition on α–β unsaturated carbonyl leading to the β sulfido ketone are reported.

创建时间:
2017-06-30
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