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Nitrone Cycloadditions to Isolevoglucosenone: Ready Access to a New Class of Directly Linked (1→3)-Imino-<i>C</i>-disaccharides

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NIAID Data Ecosystem2026-03-06 收录
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Straightforward access to a new class of d-gulo- and d-allo-derived directly linked (1→3)-imino-C-disaccharides by means of cycloaddition reactions of enantiopure polyhydroxylated pyrroline N-oxides with isolevoglucosenone is reported. The cycloaddition reactions display a high level of double asymmetric induction, which allows a partial kinetic resolution of a racemic nitrone.

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2016-08-20
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