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Synthesis of Sterically Crowded Polyarylated Boron-Dipyrromethenes

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NIAID Data Ecosystem2026-03-07 收录
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A rapid synthetic route for polyarylated boron-dipyrromethenes using hexabromo boron-dipyrromethene as the key synthon is described. The X-ray structure revealed that the polyarylated BODIPY adopts a propeller-like conformation. These compounds exhibit red-shifted absorption and fluorescence bands with decent quantum yields and reversible oxidation and reduction waves when compared to unsubstituted boron-dipyrromethenes.

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2011-10-21
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