New Ferroelectric and Nonlinear Optical Porous Coordination Polymer Constructed from a Rare (CuBr)<sub>∞</sub> Castellated Chain
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A novel three-dimensional porous coordination polymer {[CuLBr]·0.5H2O}n, solvothermally synthesized by the self-assembly of 4,4′-H2bpz (L = 4,4′-H2bpz = 3,3′,5,5′-tetramethyl-4,4′-bipyrazole) and CuBr, has a non-centrosymmetric polar packing arrangement, resulting in a strong second harmonic generation response and ferroelectric property.
创建时间：
2016-02-27
