Zirconocene−1-aza-1,3-diene complexes, [Me2Si(C5H4)2]Zr[N(Ar)CHCHCH(Ph)] (Ar = Ph, 2a; Ar = p-MeOC6H4, 2b) and Cp2Zr[N(Ar)CHCHCH(Ph)] (Ar = Ph, 3a; Ar = p-MeOC6H4, 3b), have been synthesized and cha
We characterize the stationary points along the Walden inversion, front-side attack, and double-inversion pathways of the X– + CH3Y and X– + SiH3Y [X, Y = F, Cl, Br, I] SN2 reactions using chemically
The low- and high-temperature oxidation mechanisms of n-heptane have been extensively studied in recent and past literature because of its importance as a primary reference fuel. Recent advanced analy
