Structure and Properties of New Mixed-Valent [Mn<sup>III</sup><sub>2</sub>Mn<sup>IV</sup><sub>3</sub>Ln<sup>III</sup><sub>5</sub>O<sub>5</sub>] Complexes (Ln<sup>III</sup> = Tm<sup>III</sup>, Lu<sup>III</sup>, and Yb<sup>III</sup>)
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By using 2′-hydroxyacetophenoxime, a new family of complexes with an [MnIII2MnIV3Ln5O5] core was obtained with Ln = Tm (1), Lu (2), and Yb (3). Heterometallic Mn/Tm and Mn/Lu combinations have had no precedence so far. Studies of the magnetic properties indicate the presence of intracomplex antiferromagnetic interactions in 1 and 3, as well as a dominating ferromagnetic interaction between MnIII and MnIV spins in 2, leading to an ST = 5/2 ground state.
创建时间：
2016-02-21
