A Bis-Carbyne (Ethanediylidyne) Complex via the Catalytic Demercuration of a Mercury Bis(carbido) Complex
收藏NIAID Data Ecosystem2026-03-06 收录
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Successive treatment of [Mo(CBr)(CO)2{HB(pzMe2)3}] (pz = pyrazol-1-yl) with nBuLi and mercuric chloride provides the bis(carbido)mercurial complex Hg[CMo(CO)2{HB(pzMe2)3}]2, which is catalytically demercurated by [RhCl(CO)(PPh3)2] to provide the bis-carbyne (ethanediylidyne) compound (μ-C2)[Mo(CO)2{HB(pzMe2)3}]2.
创建时间：
2016-02-26
