Fast and Reversible Intramolecular Cleavage of an Au−C Bond in the Spiked-Triangular Metal Complexes [Fe<sub>3</sub>Au(μ<sub>4</sub>,η<sup>2</sup>-C⋮C<sup>t</sup>Bu)(CO)<sub>9</sub>(PR<sub>3</sub>)] (R = Ph, <sup>i</sup>Pr)
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The C−S bond cleavage in the alkynethiolate ligand of the compound Li[Fe3(μ3-SC⋮CtBu)(CO)9] (1a) takes place in its reaction with [AuClPR3] (R = Ph, iPr), affording the complexes [Fe3Au(μ4,η2-C⋮CtBu)(CO)9(PR3)] (R = Ph (3a), iPr (3b)). The gold fragment displays an unexpected bonding mode, and a fast and reversible process of oxidative addition/reductive elimination of the Au−C bond has been observed in solution.
创建时间：
2016-08-26
